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ORIGINAL RESEARCH article

Front. Built Environ., 16 February 2023
Sec. Computational Methods in Structural Engineering
This article is part of the Research Topic Methods and Applications in Computational Methods in Structural Engineering View all 7 articles

Toward four-dimensional materials: The true nature of undamageable materials and bimodal self-regenerating materials

George Z. Voyiadjis
George Z. Voyiadjis1*Peter I. KattanPeter I. Kattan2
  • 1Department of Civil and Environmental Engineering, Louisiana State University, Baton Rouge, LA, United States
  • 2Independent Researcher, Petra Books, Amman, Jordan

The development of the theories of undamageable materials and bimodal self-regenerating materials leads directly to four-dimensional materials. Both are types of sought after materials. The authors have established that undamageable materials are the limit of Voyiadjis-Kattan materials of order n as n approaches infinity. Similarly, the authors established also that so called bimodal materials are the limit of self-regenerating materials of order n as n approaches infinity. In this work, a solid link is established between these theories that were developed recently and the new four-dimensional materials to come. It is concluded that both undamageable materials and bimodal materials are prime examples of four-dimensional materials. The conclusion is based on sound mathematical and mechanical principles.

1 Introduction

The basic principles of damage mechanics were laid out in the fifities with the pioneering work of Kachanov (1958). More recent work on this topic was made by Lee et al. (1985), Voyiadjis and Kattan (1992, 2005, 2006, 2009), Sidoroff (1981), and Kattan and Voyiadjis (1993, 2001a, 2001b).

Kachanov (1958) developed the fundamental basis of continuum damage mechanics using the concept of effective stress. More recent advancements in this topic were made by Rabotnov (1969) and by others later (Ladeveze and Lemaitre, 1984; Kattan and Voyiadjis, 2001a; 2001b; Voyiadjis and Kattan, 2005; 2006; 2009; 2012a; 2012c). The value of the damage variable ranges between 0 and 1 but usually cannot exceed 0.3. In the two extreme cases of 0 and 1, the material is in the virgin state and totally damaged, respectively.

Many advancements were made in damage mechaics recently (Rice, 1971; Sidoroff, 1981; Ladeveze et al., 1982; Lee et al., 1985; Voyiadjis, 1988; Kattan and Voyiadjis, 1990; 1993; Voyiadjis and Kattan, 1990; 1992; Hansen and Schreyer, 1994; Doghri, 2000; Luccioni and Oller, 2003; Celentano et al., 2004; Lubineau and Ladeveze, 2008; Lubineau, 2010).

Basaran and coworkers develop the theory further to apply it to novel materials (Basaran and Yan, 1998; Basaran and Tang, 2002; Basaran et al., 2003; Basaran and Nie, 2004; 2007). Other theoretical developments appeared later by Sosnovkiy and Sherbakov (2016). A relation has also been made thus far linking damage mechaics to biological systems. For details about the concept of the fourth dimension, check the Appendix.

This work consists of three major sections. In Section 2 the principles of the mechanics of undamageable materials are reviewed. The section starts with a review of higher-order strain energy form. This is followed by a study of the damage variable and the proof that the undamageable material maintains a zero value for the damage variable throughout the process of deformation and damage. Finally, the elastic stiffness equations for undamageable materials are presented.

In Section 3 the principles of the mechanics of self-regenerating materials are presented. First the theoretical formulation is reviewed. This is followed by the elastic stiffness equations and how the elastic stiffness recovers in self-regenerating materials. Finally, the road to bimodal materials is explored by studying self-regenerating materials when the exponent n goes to infinity. In this extreme case it is seen that the elastic stiffness disappears and appears suddenly again. Thus these materials at the extreme case are called bimodal materrials.

Finally in the Conclusion it is postulated that both undamageable materials and bimodal materials are types of four-dimensional materials. It is seen that when infinity is reached, a dimension is crossed and we enter into the world of four-dimensional materials.

The original issue in this work is the term “fourth-dimensional material” and its associated conepts. This term has never appeared before in the literature or anywhere else. However, the theories of undamageable materials and bimodal materials have been presented before by the authors and they review them here along with their associated concepts and equations (Voyiadjis and Kattan, 2013a; 2017d). The presentation here is brief and updates the previous work of the authors.

As it was stated in the conclusion this work addresses both the theory of undamageable materials and the theory of self-regenerating materials. In particular both the undamageable material and the proposed bimodal material are of vital interest to the manufacturing world. Both these materials are achieved mathematically as one approaches infinity. It is noted that as infinity is approached a dimension is crossed and one evolves into the four-dimensional materials. This fact was proved mathematically in the authors’ own work on the subject (Voyiadjis and Kattan, 2017c). Thus it is seen that both undamageable materials and bimodular materials are types of four-dimensional materials. This is the true nature of these hypothetical materials.

2 Mechanics of undamageable materials

In this section the mechanics of undamageable materials are reviewed. One starts with the higher-order strain energy forms, then proceeds to a study of the damage variable in these materials, then the elastic stiffness equations are presented.

2.1 Higher-order strain energy forms

Higher order strain energy forms are studied and introduced in this section. These new forms are usually linked to non-linear stress-strain relations and are studied in detail in this work These new proposed types of materials are called here Voyiadjis-Kattan materials (Voyiadjis and Kattan, 2013a, 2013b).

One first starts with the linear relation. The linear stress-strain relation σ=Eε corresponds to the classsical strain energy form U=12σε. Now, suppose higher powers of the stain are suggested in the expressions like the following 12σε2, 12σε3, What happens to the stress-strain relations in these cases? This issue is studies in the sequel.

Use will be made of the terminology by Voyiadjis-Kattan material of order n to designate any non-linear elastic material that has a higher-order strain energy of the form 12σεn.

One first starts with the most general from of the stress-strain equation: σ=Ef(ε), where f(ε) is an unknown function of the strain that is to be determined. Ther strain energy U in this case is obtained using the following equation:

U=σdε(1)

One now illustrates the general case using the higher-order strain energy form U=12σεn. Substituting this expression for U into Eq. 1, one obtains:

12σεn=σdε(2)

Next, one substitutes the general stress-strain relation σ=Ef(ε) into Eq. 2 to obtain:

12Ef(ε)εn=Ef(ε)dε(3)

Simplifying the above relation, one obtains:

f(ε)εn=2f(ε)dε(4)

Differentiating both sides of the above equations lead to the following:

f/(ε)εn+nf(ε)εn1=2f(ε)(5)

The above is the governing differential equation of the system and is solved using the MATLAB Symbolic Math Toolbox. The solution is obtained as follows:

f(ε)=1εne2/[(n1)ε(n1)](6)

Substituting the above expression into the general constitutive relation σ=Ef(ε), one obtains:

σ=E1εne2/[(n1)ε(n1)](7)

The above solution is obtained after applying the initial condition that the stress is zero when the strain is zero. The above equation is a non-linear stress-strain relationship that governs the behavior of the Voyiadjis-Kattan material of order n.

For certain selected values of n, the results are shown in Table 1. Other existing materials similar to the Voyiajdis-Kattan material are shown in Table 2. Figure 1 showns a graph of the various stress-strain relations of Table 1. Figure 1 is generated based on Eq. 7 and proper units appear on the figure.

TABLE 1
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TABLE 1. The proposed higher-order strain energy forms and their corresponding stress-strain relations (constitutive equations for Voyiadjis-Kattan material of order n).

TABLE 2
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TABLE 2. Comparison between the Voyiadjis-Kattan material of order n and other non-linear elastic materials from the literature.

FIGURE 1
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FIGURE 1. Valid stress-strain curves for various values of n.

2.2 The damage variable

One considers a linear elastic material with modulus of elasticity E. Another confiuguration of the material is considered that is fictitious with no damage with the modulus Ε¯. In order to compute the effective elastic modulus Ε¯ in this case, one may use the hypothesis of elastic energy equivalence where the elastic strain energy is assumed to be equal in both configurations (Sidoroff, 1981). Figure 2 is obtained based on Eq. 9 and Eq. 11 below. Proper units and a proper legend now appear on the figure.

FIGURE 2
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FIGURE 2. Damaged and effective moduli of elasticity.

The scalar damage variable is defined in terms of the reduction in the elastic modulus as follows:

=E¯EE(8)

where E is the elastic modulus in the damaged state while E¯ is the effective elastic modulus (in the fictitious state) with E¯>E (see Figure 2). Other researchers used the new damage variable in their wrok—Celentano et al. (2004) and Voyiadjis (1988) and Voyiadjis and Kattan (2009). The expression in Eq. 8 can be re-written as follows:

E¯=E(1+)(9)

Using the hypothesis of elastic energy equivalence one assumes the complementary elastic strain energy (σ22E ) to be equal in both configurations, i.e.,

σ22E=σ¯22E¯(10)

Using the hypothesis of elastic energy equivalence and using Eq. 10, one obtains σ¯=E¯Eσ. In this case, it can be easily shown that the damage variable =E¯EE will yield the relation σ¯=σ1+.

Postulating a new hypothesis of higher-order energy equivalence in the form

12σ2ε=12σ¯2ε¯(11a)

one consequently obtains:

σ32E=σ¯32E¯(11b)

Finally, one obtains the relation

σ¯=E¯E3(11c)

In this case, it is easily shown that using =E¯EE will yield the relation

σ¯=σ1+3(11d)

For the general case and for a general value of n, one obtains:

σ¯=E¯En(12a)

In this case, it is easily shown that using =E¯EE will yield the general relation

σ¯=σ1+n(12b)

Several curves are plotted on the same graph paper to show the relations between the ratio of the stresses σ¯σ and using Eqs 11b, 12b (see Figure 3). It is clear that for the limiting case when n, the curve has a constant value at 1. Figure 3 is generated based on Eq. 12b and proper units appear on the figure.

FIGURE 3
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FIGURE 3. Relation between 1 and the ratio of the stresses.

One now explains the above results using the formulas derived for . Starting with the formula σ¯=σ1+n of Eq. 12b which was derived in the previous paragraphs one now studies the case when n. In this case, the following is obtained:

σ¯=σ1+n=σ(1+)1n=σ(1+)1=σ(1+)0=σ1=σ(13)

Therefore one obtains σ¯=σ irrespective of the value of the damage variable . The following is a summary of the main concepts and results in this section:

1. The Voyiadjis-Kattan material of order n is a non-linear elastic material which has strain energy of the form 12σεn, where n is greater than 1.

2. The undamageable material is the limit of the Voyiadjis-Kattan material of order n as n goes to infinity.

3. The linear elastic material is a type of Voyiadjis-Kattan material of order 1.

4. In an undamageable material, the value of the stress will remain equal to zero throughout the deformation process. Also, the damage variable will be equal to zero throughout.

5. The undamageable material has zero strain energy.

6. The undamageable material has non-zero strain values. Thus, the undamageable material is a type of deformable body, not a rigid body.

7. The Voyiadjis-Kattan material of order n has non-zero stress values. The range of the non-zero stress values changes depending on the value of n. The higher the value of n, the narrower the range of non-zero stress values.

2.3 Elastic stiffness equations

In this section, the precise equations governing the elastic stiffness transformation for Voyiadjis-Kattan materials are derived (Voyiadjis and Kattan, 2013a; 2012b; 2012c; 2013b; 2014). For this derivation, use is made of the classical damage variable that is defined in terms of area reduction. In this regard, the effective stress is given by:

σ¯=σ1φ(14)

where σ is the Cauchy stress and ϕ is the classical damage variable.

Utilizing a hypothesis of higher-order energy equivalence in the following form:

12σ¯ε¯n=12σεn(15)

and substituting Eq. 14 into Eq. 15, and simplifying, one obtains the following expression for the effective strain:

ε¯n=(1φ)εn(16)

It should be noted that the stress-strain relationship for the Voyiadjis-Kattan material of order n is given by Eq. 7. Rewriting Eq. 7 in the effective fictitious configuration, one obtains:

σ¯=E¯1ε¯ne2/[(n1)ε¯(n1)](17)

Substituting for the effective stress from Eq. 14 into Eq. 17, one obtains:

σ=(1φ)E¯1ε¯ne2/[(n1)ε¯(n1)](18)

Next, substituting for the stress from Eq. 7 into Eq. 18 and simplifying the resulting equation, one obtains:

EE¯ε¯nεn=(1φ)e2/((n1)εn1)e2/((n1)ε¯n1)(19)

and furthermore substituting Eq. 16 into Eq. 19 and simplifying one obtains:

EE¯=e2ε¯n12εn1(n1)ε¯n1εn1(20)

The above relation can be re-written in the following form:

lnEE¯=2ε¯n12εn1(n1)ε¯n1εn1(21)

Again, substituting Eq. 16 into Eq. 21 and simplifying, one obtains:

lnEE¯=2[(1φ)11/n1](n1)(1φ)11/nεn1(22)

It should be noted that as one approaches infinity, a dimension is crossed and evolves into of four dimensions. Thus undamageable materials are a type of four-dimensional material. Their realization in the manufacturing technology will require work in the fourth dimension. Another type of four-dimensional materials will be the bimodal material of Section 3.3 below where infinity is approached and a dimension is crossed again.

3 Mechanics of self-regenerating materials

In this section the mechanics of self-regenerating materials are presented. One starts with the scalar formulation then this is followed by the recovery of elastic stiffness in these materials. Finally the extreme case when the exponent n goes to infinity is studied and the science of bimodal materials evolves.

3.1 Scalar formulation

Based on the recent work of the authors (Voyiadjis and Kattan, 2017a; 2017b), one utilizes a new scalar bur non-linear damage variable φ defined as follows:

φ=2φφ2(23)

It is noted from Figure 4 that both damage variables satisfy the same boundary condition but while φ is linear, the new damage variable φ is non-linear. Figure 4 is generated based on Eq. 23 and it now appears with units and a proper legend.

FIGURE 4
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FIGURE 4. Comparison between the linear and non-linear damage variables.

Based on the above equations, one can then write the following relation:

σ¯=σ1φ=σ12φφ2(24)

The values of the effective stress are real when the damage variable φ has values in the range 0<φ<2. A plot of the expression of the effective stress of Eq. 24 is shown in Figure 5 for the range of values 0<φ<2. The value of two for the damage variable is twice the rupture value of 1 for the damage variable in classical damage mechanics. However, the authors have no physical interpretation for the value of two for the damage variable.

FIGURE 5
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FIGURE 5. Effective stress behavior for self-regenerating materials.

The following observations are made regarding Figure 5 and the associated Eq. 7: Note that Figure 5 is generated based on Eq. 24 and appears with proper units.

1. The simple expression shown in Eq. 24, along with Figure 5, clearly describes a damage stage that is followed by a healing stage.

2. The behavior observed in Figure 5 is a characteristic of soft materials, especially for biological tissue.

3. The expression given in Eq. 24 is the basis for a new hypothetical type of material to be called Self-Regenerating Material (SRGM). This material may be developed in the future when the manufacturing technology may address such challenges.

4. The constitutive equations of Self-Regenerating Materials in terms of elastic stiffness are developed in Section 4.

5. Upon loading, the virgin (undamaged) material undergoes damage in the range 0<φ<1. This observed behavior continues until the material ruptures and the effective stress explodes at φ=1. The behavior in this primary stage is in accordance with the classical formulation of continuum damage mechanics and applies to currently existing materials.

6. Upon further loading, beyond φ=1, something unexpected happens. In the range 1<φ<2, some form of re-integration or re-assembly of the material occurs during a stage of healing and strengthening of the elastic modulus. This secondary stage continues until all the damage is recovered and the virgin (undamaged) material restored to its original configuration at φ=2.

7. The two boundary cases at φ=0 and φ=2 are exactly identical, and the virgin material is restored completely. In fact it is clear that the graph in Figure 5 is symmetrical around φ=1. That is why it is termed bimodular as it reverts back to its initial configuaration.

3.2 Recovery of elastic stiffness

Using the hypothesis of elastic strain equivalence, substituting the elastic constitutive relations ε=σ/E and ε¯=σ¯/E¯, along with using Eq. 24, and simplifying, one obtains the following expression for the elastic stiffness transformation:

E=E¯(12φφ2)(25)

Alternatively, using the hypothesis of elastic energy equivalence, substituting Eq. 24 into Eq. 10, and simplifying (while assuming n=1), one obtains the following expression for the elastic strain transformation:

ε¯=ε(12φφ2)(26)

Finally one obtains the following expression for the elastic stiffness in this case:

E=E¯(12φφ2)2(27)

The relations of Eqs 27, 25 are plotted in Figure 6. The results of this section are summarized in Table 3.

FIGURE 6
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FIGURE 6. Elastic stiffness degradation and recovery for the.

TABLE 3
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TABLE 3. Elastic stiffness degradation and recovery equations in the scalar case.

3.3 Toward a science of bimodal materials

Further developments of the theory derived in Section 4 for self-regenerating materials are shown in this section especially with the loss of stiffness and its further recovery. These results can be extended to the hypothetical case when n. In this case interesting results are obtained, and a new type of material emerges that can be constructed mathematically. This new limit material is termed a bimodal material.

3.4 Two hypotheses of damage mechanics

Both Eqs 25, 27 for the elastic stiffness transformation due to damage can be generalized using the following expression:

E=E¯(12φφ2)n(28)

where n is an integer exponent with n=1,2,3,4,...... It is noted that Eq. 25 of the hypothesis of elastic strain equivalence is recovered using n=1, while Eq. 27 of the hypothesis of elastic energy equivalence is recovered using n=2. The material behavior described by the generalized Eq. 11 is called a self-regenerating material of order n (see Figure 6). Note that Figure 6 is generated based on Eq. 28 and appears with proper units.

The expression of Eq. 28 is plotted in Figure 7 for several values of the integer exponent n. The special case when n is illustrated separately in Figure 6. The curve obtained in Figure 8 represents the limit of the sequence of curves appearing in Figure 7 as n. This limiting case is very interesting as it gives rise to a new type of material that has some curious and strange characteristics. It should be noted that both the self-regenerating materials of order n of Figure 7, as well as the hypothetical limit material of Figure 8 do not currently exist except as biological tissue which is explained in Section 4. Figures 7, 8 are generated based on Eq. 28 and appear with proper units.

FIGURE 7
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FIGURE 7. Elastic stiffness degradation and recovery for different values of the integer exponent n.

FIGURE 8
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FIGURE 8. Elastic stiffness behavior as n approaches infinity.

It is very interesting and paramount to observe in this section the strange behavior of the limit material of Figure 8 which naturally exists as biological tissue with its capability to fully heal itself (see Section 4) As shown in Figure 8, the elastic stiffness of this material is zero everywhere except at the two end points, i.e., at φ=0 and φ=2. This means that the stiffness of the material vanishes as soon as the loading starts and remains vanished until the final load is applied at the end of the deformation and damage process. At the final point of loading, it seems that the elastic stiffness appears suddenly, behaving in a bimodal way, to its full extent. Thus, this material exhibits vital behavior in the sense that the elastic stiffness disappears due to excessive damage at the start of loading, and biologically mends itself through tissue regeneration at the end of loading. The elastic stiffness vanishes throughout the loading process between the start point and the end point. Therefore, the material exhibiting the characteristics shown in Figure 8 is termed a bimodal material. It is emphasized that the bimodal material is the limit of the self-regenerating material of order n as n. The bimodal material does not exist currently but the basic equations governing its behavior are formulated in this work.

The main characteristics of the postulated bimodal material are summarized below based on Eq. 28 and Figure 8:

1. The bimodal material suffers a sudden drop of its elastic stiffness from E¯ to zero at the starting point of loading.

2. The bimodal material breaks down (or its elastic stiffness vanishes completely) upon the start of loading and remains in this vanished state until the end point of loading.

3. The bimodal material undergoes a sudden gain in elastic stiffness from zero to its maximum value of E¯ at the ending point of loading.

4. It seems that the elastic stiffness of the bimodal material suddenly disappears upon the start of loading and suddenly re-appears upon the end of loading. This strange behavior gives this material its name.

5. The bimodal material is the limit of the self-regenerating material of order n as n.

It should be noted that as one reaches infinity, a dimension is crossed and enters the mathematics of four dimensions. Thus this bimodal material is another type of four-dimensional materials. The first type of four-dimensional material was the undamageable material of Section 2.

4 Conclusion

This work has been divided into two major parts, existing mainly in Sections 2, 3. In Section 2 the theory of undamageable materials is presented while in Section 3 the theory of self-regenerating materials is presented. In particular both the undamageable material of Section 2 and the bimodal material of Section 3.3 are of vital interest to the manufacturing world. Both these materials are achieved mathematically as one approaches infinity. It is noted that as infinity is approached a dimension is crossed and one evolves into four-dimensional materials. This fact was proved mathematically in the authors’ own work on the subject (Voyiadjis and Kattan, 2017c). Thus it is seen that both undamageable materials and bimodal materials are types of four-dimensional materials. This is the true nature of these hypothetical materials.

As it was stated here this work addresses both the theory of undamageable materials and the theory of self-regenerating materials. In particular both the undamageable material and the proposed bimodal material are of vital interest to the manufacturing world. Both these materials are achieved mathematically as one approaches infinity. It is noted that as infinity is approached a dimension is crossed and one evolves into the four-dimensional materials. This fact was proved mathematically in the authors’ own work on the subject (Voyiadjis and Kattan, 2017c). Thus it is seen that both undamageable materials and bimodular materials are types of four-dimensional materials. This is the true nature of these hypothetical materials.

Data availability statement

The raw data supporting the conclusions of this article will be made available by the authors, without undue reservation.

Author contributions

All authors listed have made a substantial, direct, and intellectual contribution to the work and approved it for publication.

Conflict of interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Publisher’s note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

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Appendix: Explanation of the fourth dimension

In this Appendix, the authors try to explain the fourth dimension and what they mean by four-dimentional materials.

Consider a point. It has no extensions so the point is zero-dimensional. Now consider a set of n such points arranged horizontally on a straight line. Once the number of points n increases, the points get closer together. They become closer and closer with increasing n until n approaches infinity. When n approaches infinity the points become stuck together and effectively become a straight line. As n approached infinity, the points are no longer zero-dimensional but become a one-dimensional straight line. Thus a dimension is crossed when n approached infinity.

Similarly consider a straight line. It is clearly one-dimensional. Consider n such straight lines arranged in parallel. Let the number of these straight lines be n. Once n increases, the straight lines become closer together. This continues until n approaches infinity when the straight lines become stuck together in a plane. Thus as n approached infinity the straight lines are no longer one-dimensional but become a two-dimensional plane. Thus again a dimension is crossed as n approaches infinity.

The same thing happens when the crossing from a two-dimensional plane to a three-dimensional cube occurs. Consider a number n of two-dimensional planes arranged in parallel. As n increases, the planes get closer together. Once n approaches infinity the planes become stuck together and a three-dimensional cube is formed. In this case, again, a dimension is crossed when n approaches infinity. The planes are no longer two-dimensional planes but have become a three-dimensional cube.

Finally consider a three-dimensional cube. Consider n such three-dimensional cubes arranged in parallel. As the number of cubes n increases, the cubes become closer together. As n approaches infinity, the cubes become stuck into a fourth-dimensional hypercube called a tesseract. Thus as n approached infinity the cubes are no longer three-dimensional but have become a fourth-dimensional hypercube. Again, one notices that a dimension is crossed when n approaches ininity.

The same thing happens with materials. For normal three-dimensional materials everthing is normal as the exponent n is small. But when n becomes large and approaches infinity, a dimension is crossed and one obtains four-dimensional materials. Trying to explain this in terms of damage and healing, one can say that microvoids (zero dimension), microcracks (one dimensional), microflat spaces (two dimensional), microspherical spaces (three dimensional), collapse of spherical spaces into other shapes are fourth dimensional artifacts. Recovery in the same dimension implies closure of microvoids, microcracks, et. (Watson, 2003; Waston, 2006; Bower, 2009; Roizen, 2014).

Keywords: four-dimensional materials, undamageable materials, self-regenerating materials, bimodal materials, damage

Citation: Voyiadjis GZ and Kattan PI (2023) Toward four-dimensional materials: The true nature of undamageable materials and bimodal self-regenerating materials. Front. Built Environ. 9:1066525. doi: 10.3389/fbuil.2023.1066525

Received: 11 October 2022; Accepted: 07 February 2023;
Published: 16 February 2023.

Edited by:

Franco Milicchio, Roma Tre University, Italy

Reviewed by:

Rostand Moutou Pitti, Université Clermont Auvergne, France
David De Leon, Universidad Autónoma del Estado de México, Mexico

Copyright © 2023 Voyiadjis and Kattan. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

*Correspondence: George Z. Voyiadjis, dm95aWFkamlzQGVuZy5sc3UuZWR1

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